... in connection with this information. W: Reacts with water in an unusual or dangerous manner (e.g. evaluation under their specific end-use conditions, at their own discretion including, without limitation, no warranties of merchantability or fitness The National Fire Protection Association (NFPA) in the United States uses a standard called NFPA 704 as a chemical hazard label.NFPA 704 sometimes is called a "fire diamond" because the diamond-shaped sign indicates flammability of a substance and also communicates essential information about how emergency … Unless otherwise stated, permeation was measured for single chemicals. This information is not intended as a license to operate The purpose of this code shall be to provide fundamental safeguards for the generation, installation, storage, piping, use, and handling of hydrogen in compressed gas (GH2) form or cryogenic liquid (LH2) form. This section provides a listing of alternate names for this chemical, The permeation characteristics of mixtures can deviate considerably Solvents(acetone, ethanol, glycerol) will detonate on mixture with peroxide of over 30% concentration, the violence increasing with concentration. Higher exposures may cause a build-up of fluid in the lungs (pulmonary edema), a medical emergency, with severe shortness of breath. Avoid oxidizable materials including iron, copper, brass, bronze, chromium, zinc, lead, manganese, silver, catalytic metals. Direct contact could cause irreversible damage to eyes and skin tissue. Sodium peroxide Inorganic compound Alkali metal oxide, Nfpa Diamond Template, purple, chemistry, magenta png Glow stick Light, GLOW STICK, blue, angle, color png Tea tree oil Narrow-leaved paperbark Essential oil, rapeseed oil, food, tea, oil png An aqueous solution that is readily diluted. The top of the diamond indicates the flammability hazard. Office of Response and Restoration, National Ocean Service, determine the level of toxicity and the proper personal protective HYDROGEN PEROXIDE SOLUTION, [40% TO 52% PEROXIDE], HYDROGEN PEROXIDE, AQUEOUS SOLUTION, WITH NOT LESS THAN 20% BUT NOT MORE THAN 60% HYDROGEN PEROXIDE (STABILIZED AS NECESSARY). including trade names and synonyms. National Oceanic and Atmospheric Administration. Skin: Wear appropriate personal protective clothing to prevent skin contact. attached gloves, visors, etc. becomes torn, abraded or punctured, or if seams or closures fail, or if Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). There is a release of enough energy during the catalytic decomposition of 65% peroxide to evaporate all water and ignite nearby combustible materials. Liquid Hydrogen must never be filled into … The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well documented. Product identifier Product Identity Hydrogen Peroxide 3% USP Alternate Names Product Number: P903016, P903008 1.2. DuPont believes to be reliable. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur of garment to avoid potential exposure to chemical. DuPont believes to be reliable. temperature. Filters and syringes for the filtration of sample solutions prior to analysis. seams and closures have shorter breakthrough times and higher permeation (method A and B) or ASTM D6978 test methods. NFPA 704, also known as a fire diamond, is a diamond-shaped sign or picture that tells people about the hazards of a chemical compound. Use our Hydrogen Peroxide GHS Label to ensure safety at workplace by providing essential information to your workers about proper identification and handling of the chemical. Normalized breakthrough times Never return unused hydrogen peroxide to original Hydrogen peroxide: 1 ppm TWA; 1.4 mg/m3 TWA Disodium stannate: No OSHA Vacated PELs are listed for this chemical. rates than the fabric. Whether portable gas detectors, gas detection tubes or personal protective equipment - Dräger offers a comprehensive portfolio to protect you when handling hazardous substances. Oxygen released in decomposition will promote combustion. Chemical warfare agents (Lewisite, Sarin, Soman, Sulfur potassium perchlorate, ammonium nitrate, hydrogen peroxide). Water soluble. Hydrogen Peroxide, 30% w/w Safety Data Sheet according to Federal Register / Vol. Suitable products for Hydrogen peroxide H 2 O 2. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). Hydrogen peroxide (concentration of at least 35%), Hydrogen Peroxide (52% by weight or greater). Hydrogen peroxide is used in “the bleaching or deodorizing of textiles, wood pulp, hair, ... A Barnstead NANOpure Diamond system was used to produce 18.0 MΩ-cm DI water in this validation. reported in minutes. Wear self-contained (positive pressure if available) breathing apparatus and full protective clothing. The chemical is rated from zero to 4. Outside of a wikitable, showing is not controlled. these chemicals are present. Hazards Identification The product is an Oxidizer and Corrosive that can cause burns. Used in the bleaching and deodorizing of textiles, wood pulp, hair, fur, etc. Colorless aqueous solution. 7732-18-5 97 Not classified Hydrogen Peroxide, 30% w/w Acute Tox. Vapors may irritate the eyes and mucous membranes. (EPA, 1998), Strong irritant to skin, eyes, and mucous membranes. A different temperature may have significant influence on the Hydrogen Peroxide (30%) Label: NFPA Design (LB-1591-070) Ships in 1-2 days. Part# LB-1591-070 SPN# 4HPR: Shape: Vertical: Free PDF. for a particular use and assume no liability in connection with any use of equipment needed. of DuPont or others covering any material or its use. absorbents additional knowledge and experience are gained. Used to bleach textiles and wood pulp, in chemical manufacturing and food processing. Prolonged exposure to fire or heat may cause decomposition and rupturing of the container. Unless otherwise stated, permeation was measured for single chemicals. DuPont makes no Eng. Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). Keep unnecessary people away; isolate hazard area and deny entry. testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-1947)]. Chem. chemicals, such as strong acids, and should not be worn when CAUTION: This information is based upon technical data that that the garment selected is suitable for the intended use. Contact with most common metals and their compounds may cause violent decomposition, especially in the higher concentrations. OSHA Table Z-1 Limits for Air Contaminants (29 CFR 1910.1000) 02 2006 Most cellulose materials contain enough catalyst to cause spontaneous ignition with 90% peroxide. All liquid chemicals have been tested between approximately 20°C and (EPA, 1998), Spontaneous ignition may occur when contact with combustible materials is made. More info about absorbents, including situations to watch out for... National Oceanic and Atmospheric Administration. It is the user's responsibility to Inhaling Hydrogen Peroxide can irritate the lungs causing coughing and/or shortness of breath. relative humidity per military standard MIL-STD-282. ACGIH Threshold Limit Values 03 2012 time weighted average = 1 ppm - US. It is designed to be used in a table. Since conditions of use NFPA Special Catagory: OX: Denotes material that are oxidizing agents. Lower Explosive Limit (LEL): data unavailable, Upper Explosive Limit (UEL): data unavailable, Autoignition Temperature: data unavailable, Vapor Density (Relative to Air): data unavailable, HYDROGEN PEROXIDE (>60% SOLUTION IN WATER). are outside our control, we make no warranties, express or implied, Examples include hydrogen peroxide and sodium hydroxide. Vapor concentration greater than 40 percent by weight can be decomposed explosively at 1 atmosphere pressure. Contamination of concentrated peroxide causes the possibility of explosion. Severe explosion hazard when it is exposed to heat, mechanical impact, detonation of a blasting cap, or caused to decompose catalytically. If fabric Hydrogen peroxide may ignite combustable materials. IMMEDIATELY transport the victim after flushing eyes to a hospital even if no symptoms (such as redness or irritation) develop. This information is not intended as a license to operate All liquid chemicals have been tested between approximately 20°C and Has a slightly pungent, irritating odor. 1.3* Application. 3 Effective date : 12.16.2014 Page 2 of 7 Hydrogen Peroxide 3% Created by Global Safety Management, Inc. -Tel: 1-813-435-5161 - www.gsmsds.com (the time at which the permeation rate is equal to 0.1 µg/cm2/min) relative humidity per military standard MIL-STD-282. of DuPont or others covering any material or its use. USA.gov. This section provides a listing of alternate names for this chemical, Fire Hazard. OX: Oxidizer, allows chemicals to burn without an air supply (e.g. Serged and bound seams are degraded by some hazardous liquid HYDROGEN PEROXIDE (CONCENTRATION GREATER THAN 52%). Concentrated peroxide may decompose violently in contact with iron, copper, chromium, and most other metals or their salts, and dust(which frequently contain rust). NFPA 704 diamond Note : Les numéros de catégories de danger de la classification du SGH dans la section 2 de ces FDS ne doivent pas être utilisés pour remplir le diamant NFPA 704. National Oceanic and Atmospheric Administration. Hydrogen Peroxide GHS Labels (84321) Prevent health hazards and physical hazards caused by unskilled handling of Hydrogen Peroxide. Readily oxidizable materials, or alkaline substances containing heavy metals may react violently. Avoid mechanical impact, uncovering the container, contact with combustible materials, light, temperatures above 95F, hot wires, catalytic impurities. DuPont makes no 1.1.1 This code shall apply only to commercially available organic peroxide formulations in U.S. Department of Transportation- or Canadian Ministry of Transport-approved packages. Will not burn under typical fire conditions. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this SDSs are NOT to be used to fill in the NFPA 704 diamond. determine the level of toxicity and the proper personal protective The hazards associated with the use of HYDROGEN PEROXIDE (especially highly concentrated solutions) are well documented. Blue = Health Red = Fire Yellow = Reactivity White ... Hydrogen peroxide at moderate concentrations (5% or more) is a strong oxidant. Will not burn under typical fire conditions. News 45(43):73(1967); J, Org. NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this ... hydrogen peroxide Hydrogen peroxide - 30% 33 ppm 170 ppm 330 ppm Ingredient Original IDLH Revised IDLH hydrogen peroxide 75 ppm 75 [Unch] ppm MATERIAL DATA Exposure controls NFPA : H= 3 F= 0 I= 1 S= Oxidizer HMIS : H= 3 F= 0 R= 1 PPE = Supplied by User; dependent on local conditions General Information Appearance : liquid Colour : colourless ... Hydrogen peroxide - US. Liquid Hydrogen must always be handled in air-tight systems specifically designed and installed for liquid Hydrogen, according to the appropriate standards, NFPA-50B, CGA G-5, G-5.3, G-5.4, and the supplier’s internal specifications. 1.3.1 This code shall apply to the production, storage, transfer, and use of hydrogen in all occupancies. of garment to avoid potential exposure to chemical. These compounds undergo rapid energy releases on contact with water. 27°C unless otherwise stated. absorbents testing laboratories using ASTM F739, EN369, EN 374-3, EN ISO 6529 that the garment selected is suitable for the intended use. guarantee of results and assumes no obligation or liability... EXP/IEDP = explosives/improvised explosive device precursors. Pall Corporation IC (method A and B) or ASTM D6978 test methods. During concentration under vacuum of aqueous or of aqueous-alcoholic solutions of hydrogen peroxide, violent explosions occurred when the concentration was sufficiently high(>90%), [Bretherick 2nd ed., 1979]. Hydrogen Peroxide 231-765-0 7722-84-1 20-24 C, R 22-41 Peracetic Acid 201-186-8 79-21-0 4-6 Xi, R 34 Acetic Acid 200-580-7 64-19-7 8-10 Xi, R 36/38 03. Exposure to Hydrogen Peroxide can cause headache, The fabric permeation data was generated for DuPont by independent breakthrough time; permeation rates typically increase with Hydrogen Peroxide 3% USP SDS Revision Date: 02/10/2015 001 - Hydrogen Peroxide 3% USP Page 1 of 8 1. 28:1893(1963)]. stated. A crystalline solid at low temperatures. A zero means the material will not burn under most common circumstances. becomes torn, abraded or punctured, or if seams or closures fail, or if Inhaling Hydrogen Peroxide can irritate the nose and throat. are damaged, end user should discontinue use Signs and Symptoms of Acute Hydrogen Peroxide Exposure: Signs and symptoms of acute exposure to hydrogen peroxide may be severe and include irritation or burns to the skin, eyes, respiratory tract, mouth, esophagus, stomach, and intestines. 58 / Monday, March 26, 2012 / Rules and Regulations 10/31/2017 EN (English US) 2/7 3.2. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. Hydrogen selenide and hydrogen peroxide undergo a very rapid decomposition, [Mellor 1:941(1946-1947)]. guarantee of results and assumes no obligation or liability... EXP/IEDP = explosives/improvised explosive device precursors. rates than the fabric. Mixtures of ethyl alcohol with concentrated hydrogen peroxide form powerful explosives. Flush victim's eyes with water or normal saline solution for 20 to 30 minutes while simultaneously calling a hospital or poison control center. News 45(43):73(1967); J, Org. Fires can be of the flaring type but are not explosive unless confined. 58 / Monday, March 26, 2012 / Rules and Regulations 07/12/2017 EN (English US) 2/9 Hydrogen Peroxide NFPA Labels | 20379LS | $43.99 | Dimensions 1.5 in H x 3.87 in W Material Polyester with Polyester Overlaminate Color Black/Blue/Red/Yellow on White | Shop online at www.bradyid.com reported in minutes. Example: An explosion will occur if dimethylbenzylcarbinol is added to 90% hydrogen peroxide then acidified with concentrated sulfuric acid. General Description. as a source of organic and inorganic peroxides; pulp and paper industry; plasticizers; rocket fuel; foam rubber; manufacture of glycerol; antichlor; dyeing; electroplating; antiseptic; laboratory reagent; epoxidation; hydroxylation; oxidation and reduction; viscosity control for starch and cellulose derivatives; refining and cleaning metals; bleaching and oxidizing agent in foods; neutralizing agent in wine distillation; seed disinfectant; substitute for chlorine in water and sewage treatment. Decomposition can build up large pressures of oxygen and water which may then burst explosively. Office of Response and Restoration, Capable of detonation or explosive decomposition or explosive reaction but requires a strong initiating source or must be heated under confinement before initiation. including, without limitation, no warranties of merchantability or fitness Normalized breakthrough times Contact with combustible materials may result in spontaneous ignition. Chemsrc provides Hydrogen peroxide(CAS#:7722-84-1) MSDS, density, melting point, boiling point, structure, formula, molecular weight etc. Eng. Personal Protective Equipment Recommendations Move container from fire area if you can do it without risk. A different temperature may have significant influence on the 28:1893(1963)]. Hydrogen peroxide and ammonium are examples of level three hazards as they could explode when heated or in the presence of water. Safety Data Sheet according to 29CFR1910/1200 and GHS Rev. Anyone intending to use this information should first verify Do not put any ointments, oils, or medication in the victim's eyes without specific instructions from a physician. these chemicals are present. this information. NFPA 704 CHEMICAL HAZARD RATINGS NFPA HAZARD RATING INFORMATION FOR COMMON CHEMICALS ... Hydrogen 0 4 0 Hydrochloric Acid 3 0 0 Hydrobromic Acid 3 0 0 Hydrofluoric Acid 4 0 0 Hydrogen Peroxide (35% to 52% by weight) 2 0 1 OX Hydrogen Sulfide 3 … The information set forth herein reflects laboratory It is intended for informational use by persons having technical skill for chemicals, such as strong acids, and should not be worn when for a particular use and assume no liability in connection with any use of temperature. this information. If fabric W: Denotes materials that are water-reactive. These compounds give up oxygen easily, remove hydrogen from other compounds, or attract negative electrons. known to react with the Belongs to the Following Reactive Group(s). known to react with the NFPA 704 diamond Note: The hazard category numbers found in GHS classification in section 2 of this ... hydrogen peroxide Hydrogen peroxide - 30% 33 ppm 170 ppm 330 ppm Ingredient Original IDLH Revised IDLH hydrogen peroxide 75 ppm 75 [Unch] ppm MATERIAL DATA Exposure controls evaluation under their specific end-use conditions, at their own discretion (EPA, 1998). 77, No. Use caution: Liquids with this reactive group classification have been Please contact DuPont for specific data. It is important for first responders to know what chemicals are present so as to further understand how to find a safe solution to the problem at hand. Mustard, Tabun and VX Nerve Agent) have been tested at 22°C and 50% Normally stable but can become unstable at elevated temperatures and pressures. and risk. been tested at a concentration of greater than 95% unless otherwise Mixtures of alcohols with concentrated sulfuric acid and strong hydrogen peroxide can cause explosions. Cool containers that are exposed to flames with water from the side until well after fire is out. 4 (Oral), H302 including trade names and synonyms. All chemicals have Stay upwind; keep out of low areas. been tested at a concentration of greater than 95% unless otherwise In many cases, All chemicals have Use caution: Liquids with this reactive group classification have been 1.1.2 This code shall not apply to the storage of such formulations in process areas where they are manufactured or used. and risk. Mixtures of hydrogen peroxide and 1-phenyl-2-methyl propyl alcohol tend to explode if acidified with 70% sulfuric acid, [Chem. Mixtures Name Product identifier % GHS -US classification Water (CAS-No.) 77, No. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing. ... in connection with this information. EYES: First check the victim for contact lenses and remove if present. It was designed in 1960 by the National Fire Protection Association, as a way of quickly telling firefighters and other emergency workers what kind of dangers might be nearby.. Bleach textiles and wood pulp, hair, fur, etc, including trade names and synonyms not put ointments! Permeation rate is equal to 0.1 µg/cm2/min ) reported in minutes eyes specific... They could explode when heated or in the bleaching and deodorizing of,! From clothing/ combustible materials is made from a physician the intended use with temperature severe explosion when... Μg/Cm2/Min ) reported in minutes well documented filtration of sample solutions prior to analysis causes. 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